Open AccessA model for producing polymer stabilizers of composites with a given macromolecule composition
Author(s) -
С. С. Глазков,
Д. С. Глазков,
Vladimir Kozlov,
I. F. Shutilin
Publication year - 2020
Publication title -
vestnik voronežskogo gosudarstvennogo universiteta inženernyh tehnologij
Language(s) - English
Resource type - Journals
eISSN - 2310-1202
pISSN - 2226-910X
DOI - 10.20914/2310-1202-2020-1-262-266
Subject(s) - comonomer , copolymer , monomer , materials science , thermodynamics , polymer chemistry , reactivity (psychology) , polymer , macromolecule , kinetics , chemistry , composite material , physics , medicine , biochemistry , alternative medicine , pathology , quantum mechanics
An attempt has been made to obtain a working technological formula that regulates the addition of comonomer over time, which ensures the synthesis of a copolymer macromolecule with a constant composition and, accordingly, with predicted properties of both the copolymer and its modified porous composite materials. Mathematical modeling is based on the theory of the kinetics of copolymerization, which takes into account the reactivity of monomers by means of copolymerization constants of reacting comonomers. The starting base was the kinetics of the copolymerization of two comonomers, significantly differing in their reactivity, which required a sequential, stepwise supply of a less reactive monomer to the reaction medium with a more active monomer. This technological technique contributes to maintaining the constancy of the initial ratio of comonomers and, accordingly, the synthesis of a copolymer with a constant composition, structure and properties. The dependence of the sequence of supply of comonomer to the reaction medium required the introduction of a generalized effective binary copolymerization rate coefficient. To find the generalized coefficient of the copolymerization rate, the operation of logarithm was performed and the current expression of the dependence of the concentration change of the more active monomer in time in a linear form was translated. This mathematical technique made it possible to use software to process reference information to obtain the necessary coefficients for the working formula. As a result of mathematical modeling using the basic principles of binary copolymerization, the law of effective masses, and the least squares method, a working formula is obtained that allows one to regulate the given introduction of a less active monomer into the reaction medium in time. The model is analyzed using background information, the basic concepts of binary copolymerization and can be used in technological calculations when producing copolymers with specified characteristics in composition and structure.