Open AccessA Reaction of 4, 5-Diphenylimidazole Nitration in the Presence of Some 3d-Metals Nitrates
Author(s) -
I. Voda,
V. Druta,
C. Indricean,
I. Ciumacov,
Constantin Turta
Publication year - 2012
Publication title -
chemistry journal of moldova
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.275
H-Index - 5
eISSN - 2345-1688
pISSN - 1857-1727
DOI - 10.19261/cjm.2012.07(2).05
Subject(s) - chemistry , imidazole , nitration , cobalt , metal , zinc , inorganic chemistry , nickel , methanol , octahedron , ligand (biochemistry) , nitrogen atom , metal ions in aqueous solution , nitrate , derivative (finance) , dithiocarbamate , coordination complex , ion , medicinal chemistry , ring (chemistry) , organic chemistry , biochemistry , receptor , financial economics , economics
By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Metal ions have a distorted octahedral environment with N2O4. Coordination number of metal is six. Ligand is coordinated to metal ion by one oxygen atom of nitrogroup and one nitrogen atom of imidazole.