Open Access(-)-Sclareol Conversion in Ritter's Reaction Conditions
Author(s) -
S. S. Koval’skaya,
Н. Г. Козлов,
Aculina Aricu,
Veaceslav Kulciţki,
Nicon Ungur
Publication year - 2012
Publication title -
chemistry journal of moldova
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.275
H-Index - 5
eISSN - 2345-1688
pISSN - 1857-1727
DOI - 10.19261/cjm.2012.07(2).01
Subject(s) - ritter reaction , chemistry , nitrogen atom , organic chemistry , catalysis , ring (chemistry)
The main products of sclareol (1) Ritter’s reaction in mild conditions are (8R,13R)-Labd-14(15)-en-8,13-diacetamide (2) (8R,13S)-Labd-14(15)-en-8,13-diacetamide (3) stereoisomeric on C13 atom and having unrearranged native diol skeleton. We present in the current communication the results of sclareol converting (1) into nitrogen-containing labdanes in the Ritter’s reaction conditions.