Magnetic Investigation of an Unusual Dissymmetric Binuclear Manganese Carboxylate Complex | Zendy

Ghénadie Novitchi | Zendy; JeanPierre Costes | Zendy; Lilia Popovschi | Zendy; Sergiu Shova | Zendy; Аurelian Gulea | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Magnetic Investigation of an Unusual Dissymmetric Binuclear Manganese Carboxylate Complex

Author(s) -

Ghénadie Novitchi,

JeanPierre Costes,

Lilia Popovschi,

Sergiu Shova,

Аurelian Gulea

Publication year - 2006

Publication title -

chemistry journal of moldova

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.275

H-Index - 5

eISSN - 2345-1688

pISSN - 1857-1727

DOI - 10.19261/cjm.2006.01(1).03

Subject(s) - chemistry , manganese , antiferromagnetism , carboxylate , hamiltonian (control theory) , condensed matter physics , crystallography , nuclear magnetic resonance , stereochemistry , physics , organic chemistry , mathematical optimization , mathematics

The magnetic susceptibility (χT) of an unusual dissymmetric binuclear manganese corboxylate complex has been measured from 2 to 300K. The magnetic data which have been fitted with help of the Heisenberg Dirac Van Vleck HDVV spin-exchange Hamiltonian H = − J S 1 S 2 , indicate that an antiferromagnetic interaction equal to J = -0.90(1) cm-1 is present. A correlation between J values and Mn-H2O-Mn angles has been tempted.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research