Premium
Dynamic in‐stream fate modeling of xenobiotic organic compounds: A case study of linear alkylbenzene sulfonates in the Lambro River, Italy
Author(s) -
Deksissa Tolessa,
De Pauw Dirk,
Vanrolleghem Peter A.
Publication year - 2004
Publication title -
environmental toxicology and chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.1
H-Index - 171
eISSN - 1552-8618
pISSN - 0730-7268
DOI - 10.1897/03-466
Subject(s) - linear alkylbenzene , benthic zone , environmental science , sorption , sediment , environmental chemistry , water quality , hydrology (agriculture) , chemistry , ecology , geology , biology , pulmonary surfactant , biochemistry , paleontology , geotechnical engineering , organic chemistry , adsorption
Using a conceptual hydraulic model, a one‐dimensional dynamic river water quality model has been developed to assess the short‐term fate of linear alkylbenzene sulfonates (LAS) in the river compartments water and benthic sediment. The model assumes local equilibrium sorption and that both dissolved and sorbed chemical are available for biodegradation. To investigate the interaction of nutrient dynamics and organic contaminant fate, the model is coupled with a basic water quality model. On the basis of the Lambro River (Italy) as a case study, the result shows that the model predictions agree well with the measured data set. The model output sensitivity to model parameters has been tested, and the results depict that the model is highly sensitive to the biodegrading parameters. Also, a comparison of a steady state with a dynamic simulation and the effect of nutrient dynamics on the LAS fate in the Lambro River as a scenario analysis are presented. The results indicate the usefulness of the proposed model for the short‐term simulation of organic contaminant fate in unsteady environmental conditions.