P‐189: Vapor Pressures of Homo‐ and Heteroleptic Orthometalated Complexes of Iridium | Zendy

Deaton Joseph C. | Zendy; Huo Shouquan | Zendy; Lussier Barbara B. | Zendy; Brown Christopher T. | Zendy; Garnett Joy C. | Zendy; Blondell Debra B. | Zendy; Landry Michael R. | Zendy

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P‐189: Vapor Pressures of Homo‐ and Heteroleptic Orthometalated Complexes of Iridium

Author(s) -

Deaton Joseph C.,

Huo Shouquan,

Lussier Barbara B.,

Brown Christopher T.,

Garnett Joy C.,

Blondell Debra B.,

Landry Michael R.

Publication year - 2006

Publication title -

sid symposium digest of technical papers

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.351

H-Index - 44

eISSN - 2168-0159

pISSN - 0097-966X

DOI - 10.1889/1.2433676

Subject(s) - iridium , phosphorescence , sublimation (psychology) , dopant , enthalpy of sublimation , enthalpy , chemistry , materials science , thermodynamics , doping , standard enthalpy of formation , organic chemistry , physics , fluorescence , catalysis , optoelectronics , psychology , quantum mechanics , psychotherapist

Tris‐orthometalated complexes of iridium are the leading class of phosphorescent dopants for use in harvesting triplet state emission in OLEDs. Here we report vapor pressures of a group of homo‐ and heteroleptic orthometalated iridium complexes and derive the enthalpies and entropies of sublimation. Molecular features influencing these thermodynamic properties are discussed. Keywords: phosphorescent emitter, iridium complexes, sublimation, vapor pressures, enthalpy, entropy.

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