Open AccessSORPTION OF ERYTHROSINE ONTO SILICA GEL MODIFIED BY CETYLPYRIDINIUM BROMIDE
Author(s) -
Olena Guzenko,
Olena Zhukovetska,
D. M. Mukienko,
V. V. Shopovalenko,
А. Н. Чеботарев,
Denys Snigur
Publication year - 2021
Publication title -
vìsnik odesʹkogo nacìonalʹnogo unìversitetu. hìmìâ
Language(s) - English
Resource type - Journals
eISSN - 2414-5963
pISSN - 2304-0947
DOI - 10.18524/2304-0947.2021.3(79).240755
Subject(s) - sorption , sorbent , chemistry , silica gel , desorption , langmuir adsorption model , adsorption , aqueous solution , erythrosine , sodium hydroxide , inorganic chemistry , nuclear chemistry , chromatography , organic chemistry
In the current paper, adsorbent based on silica gel L 40/100 modified with cetylpyridinium bromide was obtained. The presence of cetylpyridinium cations on the silica gel surface was confirmed by the diffuse reflectance infrared fourier transform spectroscopy method. The sorption conditions of erythrosine from dilute aqueous solutions with the proposed sorbent were studied and optimized. It is shown that the use of modified silica gel allows efficient (>95%) extraction of erythrosine from aqueous solutions. Under optimal sorption conditions (pH 7, sorbent dosage 0.1 g and sorption time is 15 min), the sorption capacity of modified erythrosine sorbents was determined. It is shown that, with increasing temperature, a change in the isotherm type from the H‑type to the L‑type is observed. This change can be explained by the aggregation of erythrosin in solution, which is a competitive sorption process. It was shown that adsorption isotherms were well described by the Langmuir equation. Thermodynamic studies have made it possible to establish the spontaneous sorption. The desorption of erythrosine from the surface of silica gel modified with cetylpyridinium bromide was studied. It is shown that when using solutions of sulfuric acid, sodium hydroxide and distilled water, desorption does not occur. It was shown that the most effective eluent is solution of sodium dodecylsulfate in alkaline medium, and desorption of erythrosine occurs due to the destruction of ion pairs of dye anions with cetylpyridinium cations fixed on the surface. The data obtained can then be used to develop a test system for determination of erythrosine via corresponding colorimetric scales or for quantitative solid phase extraction and adsorption-spectroscopic quantification of erythrosine in some real samples.