Open AccessInteraction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type. Communication 2.
Author(s) -
G. D. Zakumbaeva,
L.B. Shapovalova,
A.A. Shurtbaeva
Publication year - 2016
Publication title -
eurasian chemico-technological journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 9
eISSN - 2522-4867
pISSN - 1562-3920
DOI - 10.18321/ectj368
Subject(s) - catalysis , olefin fiber , chemistry , acetone , propene , adsorption , propanol , ruthenium , molecule , inorganic chemistry , organic chemistry , methanol
The interaction between propylene and H 2 O on Ru-Co/SiO 2 -catalyst was studied. It was determined that the process of the water addition to olefin molecule is carried out with n-propanol, i-propanol and acetone formation. For clarification of the adsorption mechanism of propylene on Ru-Co-clusters the quantum- chemical calculation of interaction between it and Ru-Co, Ru-Ru, Co-Co clusters were carried out.