Open AccessQuasi-Periodic Noise Oscillations in Oxyhydrates of Rare-Earth Elements
Author(s) -
Y. I. Sucharev,
B. A. Markov,
Tatiana I. Prolubnikova,
И. И. Лебедева
Publication year - 2011
Publication title -
eurasian chemico-technological journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 9
eISSN - 2522-4867
pISSN - 1562-3920
DOI - 10.18321/ectj101
Subject(s) - chemical physics , zirconium , magnetic field , non equilibrium thermodynamics , electrophoresis , field (mathematics) , condensed matter physics , polymer , physics , phenomenon , materials science , thermodynamics , chemistry , nuclear magnetic resonance , quantum mechanics , mathematics , chromatography , pure mathematics , metallurgy
The present paper dwells upon the chemical foundations of formation of a gel nanostructure (by the example of zirconium oxyhydrate) at the time of formation of oxyhydrate polymer chain and develops electrophoretic (diffusional) conceptions related to the phenomenon of self-organization of nonequilibrium oxyhydrate gel. Adduced are the experimental data (measurements of spontaneous current induced by the alterations in capacity of the polarized double electrical layer of the gel) that permit to claim that the mathematical model of the phenomenon is not in contradiction with the experiment. On the ground of the experimental data and calculations it is concluded that the constant magnetic field alters the character of geometrical configuration of chemical interaction of the oxyhydrate gel fragments with each other, which affects the value of nano-current measured in the course of the experiment.