Open AccessMicrowave-Assisted Pyrolysis of Cashew Nut Shell
Author(s) -
Novriany Amaliyah,
Andi Erwin Eka Putra
Publication year - 2021
Publication title -
international journal of design and nature and ecodynamics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.193
H-Index - 13
eISSN - 1755-7445
pISSN - 1755-7437
DOI - 10.18280/ijdne.160213
Subject(s) - pyrolysis , thermogravimetric analysis , char , chemistry , fourier transform infrared spectroscopy , nuclear chemistry , materials science , chromatography , analytical chemistry (journal) , organic chemistry , chemical engineering , engineering
This research examines the characteristics of microwave assisted pyrolysis products of cashew nutshell waste (CNS). The pyrolysis process of CNS conducted with microwave heating of 400 W for 60 minutes. Pyrolysis product such as bio-gas, bio-oil and bio-char were identified using proximate and ultimate analysis, scanning electron microscope (SEM), thermogravimetric analysis (TGA/DTG), gas chromatograph-mass spectrometer (GC-MS) and Fourier Transform InfraRed (FTIR) Method. There is a significant increasing in volatile matter and fixed carbon of derived bio-char and the porous structure was observed in a range of macropore after pyrolysis. The TGA profile reveals CNS sample lost about 71.25% of mass before reached 750℃. The highest decomposition rate on the DTG profile was 0.57 mg/min and 0.56 mg/min as observed at about 261.2℃ and 340.3℃. Bio-oil yield has density of 1.036 gr/ml, viscosity of 19.5 cst after water removing, flash point of 138℃ and HHV of 21.7 MJ/kg. The GC-MS of the bio-oil shows about 53% phenol, 19% palmitic and oleic acid, 11% cyclobutene, 14% ethyl and methyl ester, and cyclopentene and cyclohexane in small amounts in accordance with FT-IR results.