Open AccessNonlocal approach to thermodynamics of mixtures
Author(s) -
V. P. Maikov,
А. И. Балунов
Publication year - 2013
Publication title -
izvestiâ mgtu "mami"
Language(s) - English
Resource type - Journals
eISSN - 2949-1428
pISSN - 2074-0530
DOI - 10.17816/2074-0530-67882
Subject(s) - laws of thermodynamics , thermodynamics , entropy (arrow of time) , non equilibrium thermodynamics , extended irreversible thermodynamics , statistical physics , on the equilibrium of heterogeneous substances , basis (linear algebra) , generalization , second law of thermodynamics , entropy in thermodynamics and information theory , thermodynamic equations , mathematics , physics , maximum entropy thermodynamics , principle of maximum entropy , binary entropy function , mathematical analysis , geometry , statistics
The paper examines the highlights of mixture theory on the basis of generalized nonlocal (discrete) thermodynamics that involves Shannon entropy. Generalization of the equilibrium thermodynamics is obtained basing on the hypothesis of quantized entropy. The paper defines the elemental macroscopic thermodynamics space that serves as the basis of the mixture theory. The theory allows to use generalized thermodynamic method instead of empirical equations including laws of Raul and Dalton.