Open AccessCarbonium vs. carbenium ion-like transition state geometries for carbocation cyclization – how strain associated with bridging affects 5-exo vs. 6-endo selectivity
Author(s) -
Osvaldo Gutiérrez,
Jason G. Harrison,
Ryan J. Felix,
Fernando Cortés Guzmán,
Michel R. Gagné,
Dean J. Tantillo
Publication year - 2013
Publication title -
carolina digital repository (university of north carolina at chapel hill)
Language(s) - English
DOI - 10.17615/341c-1n32
Subject(s) - carbocation , carbonium ion , bridging (networking) , selectivity , chemistry , ion , strain (injury) , transition state , photochemistry , stereochemistry , organic chemistry , catalysis , biology , computer science , computer network , anatomy