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Mechanical Strength Enhancement of Porous Nanocrystalline-Silicon (pnc-Si) Membrane via Titanium-oxide (Ti-O) Coating
Author(s) -
Rhonira Latif,
Muhammad Fahmi bin Jaafar,
Mohd Faizal Aziz,
Burhanuddin Yeop Majlis
Publication year - 2020
Publication title -
sains malaysiana
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.251
H-Index - 29
eISSN - 2735-0118
pISSN - 0126-6039
DOI - 10.17576/jsm-2020-4912-20
Subject(s) - materials science , membrane , nanoindentation , composite material , silicon , flexural strength , titanium , layer (electronics) , nanocrystalline material , chemical engineering , nanotechnology , metallurgy , chemistry , engineering , biochemistry
Porous nanocrystalline silicon (pnc-Si) membrane is mainly studied as a blood filtration membrane, mimicking the glomerulus filtration membrane of a human kidney. However, the pnc-Si material itself is not hemocompatible and enormous membrane area to thickness ratio makes the membrane to be easily fractured. Silicon surface modification via titanium-oxide (Ti-O) thin film layer deposition has been proven to be hemocompatible and the presence of Ti-O layer has been numerically studied to give higher membrane flexural strength. In this work, square pnc-Si membranes of 2 mm × 2 mm × 20 nm size have been fabricated with and without Ti-O layer. Point loading-unloading nanoindentation method has been performed and the membranes’ displacement behaviour subjected to point loads is studied. The pnc-Si membranes with Ti-O layer were found to attain higher fracture strength, membrane bending stiffness and average hardness with the increase of ~20, ~11 and ~24%, respectively, compared to bare pnc-Si membranes. The mechanical strength of a free-standing pnc-Si membrane is improved by depositing a Ti-O thin film layer on the membrane structure.

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