A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure | Zendy

Marta Počkaj | Zendy; Nives Kitanovski | Zendy

Open Access

A Novel Tetranuclear Silver Compound with bis(3,5-dimethylpyrazol-1-yl)acetate: a Simple Synthesis Yielding Complex Crystal Structure

Author(s) -

Marta Počkaj,

Nives Kitanovski

Publication year - 2021

Publication title -

acta chimica slovenica

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.289

H-Index - 46

eISSN - 1580-3155

pISSN - 1318-0207

DOI - 10.17344/acsi.2021.6961

Subject(s) - chemistry , aqueous solution , thermogravimetric analysis , acetic acid , crystal structure , potassium hydroxide , infrared spectroscopy , elemental analysis , single crystal , silver nitrate , nuclear chemistry , inorganic chemistry , crystal (programming language) , crystallography , organic chemistry , computer science , programming language

A novel tetranuclear silver coordination compound with the formula [Ag4(bdmpza)4]·10H2O (bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate) was synthesized by a reaction between an aqueous solution of silver nitrate and an aqueous solution prepared by bis(3,5-dimethylpyrazol-1-yl)acetic acid and potassium hydroxide (1:1 molar ratio). The obtained compound was characterized by elemental analysis, coupled thermogravimetric–mass spectrometry analysis, vibrational IR spectroscopy, and its crystal structure was determined by single-crystal X-ray diffraction method. Furthermore, the obtained crystal structure was additionally evaluated by Hirshfeld surface analysis.

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