Open AccessSynthesis, Crystal Structure and Catalytic Property of a Cobalt(III) Compound Derived From 2-Bromo-N’-(2-Hydroxy-5-Methylbenzylidene)Benzohydrazide
Author(s) -
Fuming Wang
Publication year - 2016
Publication title -
acta chimica slovenica
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.289
H-Index - 46
eISSN - 1580-3155
pISSN - 1318-0207
DOI - 10.17344/acsi.2016.2520
Subject(s) - schiff base , monoclinic crystal system , chemistry , cobalt , octahedron , catalysis , cyclohexene , ligand (biochemistry) , crystal structure , crystallography , styrene , infrared spectroscopy , coordination sphere , single crystal , inorganic chemistry , organic chemistry , copolymer , biochemistry , receptor , polymer
With a tridentate Schiff base ligand 2-bromo-N'-(2-hydroxy-5-methylbenzylidene)benzohydrazide (HL) and cobalt nitrate, a cobalt(II) compound [Co(L)2]NO3 · ½H2O (1) was prepared and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. The compound crystallizes in the monoclinic space group P2(1)/c. Single crystal X-ray diffraction analysis reveals that the Co atom is coordinated by the NOO donor atoms of the Schiff base ligands, in an octahedral coordination. The compound show effective catalytic oxidation property on some olefins. In general, oxidation.