Hydroxylammonium Tetrafluoridooxidovanadate(V) – (NH3OH)[VOF4] | Zendy

Matic Lozinšek | Zendy

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Hydroxylammonium Tetrafluoridooxidovanadate(V) – (NH3OH)[VOF4]

Author(s) -

Matic Lozinšek

Publication year - 2015

Publication title -

acta chimica slovenica

Language(s) - Uncategorized

Resource type - Journals

SCImago Journal Rank - 0.289

H-Index - 46

eISSN - 1580-3155

pISSN - 1318-0207

DOI - 10.17344/acsi.2015.1424

Subject(s) - monoclinic crystal system , anhydrous , hydrogen bond , raman spectroscopy , chemistry , solvent , crystallography , crystal (programming language) , solid state , crystal structure , infrared spectroscopy , molecule , organic chemistry , physics , programming language , computer science , optics

Hydroxylammonium tetrafluoridooxidovanadate(V) has been prepared by reaction of (NH3OH)Cl and VOF3 in anhydrous HF solvent and characterised in the solid state by single-crystal X-ray diffraction and Raman spectroscopy. Colourless (NH3OH)[VOF4] crystallises in the monoclinic P21/n space group with a = 7.2349(2) Å, b = 5.0351(2) Å, c = 12.8322(4) Å, β = 94.843(3)°, V = 465.79(3) Å3 and Z = 4 at 150 K. The crystal structure of the title compound is comprised of polymeric chain anions, [VOF4]nn-, interconnected by hydrogen bonds with hydroxylammonium cations, (NH3OH)+.

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