Open AccessHydroxylammonium Tetrafluoridooxidovanadate(V) – (NH3OH)[VOF4]
Author(s) -
Matic Lozinšek
Publication year - 2015
Publication title -
acta chimica slovenica
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 0.289
H-Index - 46
eISSN - 1580-3155
pISSN - 1318-0207
DOI - 10.17344/acsi.2015.1424
Subject(s) - monoclinic crystal system , anhydrous , hydrogen bond , raman spectroscopy , chemistry , solvent , crystallography , crystal (programming language) , solid state , crystal structure , infrared spectroscopy , molecule , organic chemistry , physics , programming language , computer science , optics
Hydroxylammonium tetrafluoridooxidovanadate(V) has been prepared by reaction of (NH3OH)Cl and VOF3 in anhydrous HF solvent and characterised in the solid state by single-crystal X-ray diffraction and Raman spectroscopy. Colourless (NH3OH)[VOF4] crystallises in the monoclinic P21/n space group with a = 7.2349(2) Å, b = 5.0351(2) Å, c = 12.8322(4) Å, β = 94.843(3)°, V = 465.79(3) Å3 and Z = 4 at 150 K. The crystal structure of the title compound is comprised of polymeric chain anions, [VOF4]nn-, interconnected by hydrogen bonds with hydroxylammonium cations, (NH3OH)+.