Open AccessSupramolecular Potential of Vanadium β-Diketonate and Picolinate Compounds and The First One-dimensional Oxidovanadium(IV) Complex with β-Diketonate Ligand
Author(s) -
Tanja Koleša Dobravc,
Anton Meden,
Franc Perdih
Publication year - 2015
Publication title -
acta chimica slovenica
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.289
H-Index - 46
eISSN - 1580-3155
pISSN - 1318-0207
DOI - 10.17344/acsi.2014.1041
Subject(s) - chemistry , vanadium , ligand (biochemistry) , supramolecular chemistry , octahedron , crystal structure , crystallography , stereochemistry , hydrogen bond , molecule , inorganic chemistry , organic chemistry , receptor , biochemistry
Three vanadium compounds with β-diketonato or picolinato ligands were prepared and structurally characterized. In compounds [VO(tfpb)2]∞ (1) (tfpb = 4,4,4-trifluoro-1-phenylbutane-1,3-dionate) and [VO(acac)2(2-pyridone)] (2) the coordination of vanadium atom is octahedral and in the compound Hpy[VO2(pic)Cl] (3) the central atom is pentacoordinated. X-Ray crystallographic studies reveal infinite chain formation due to V=O···V=O interactions in 1, while 2 and 3 are mononuclear compounds. Centrosymmetric hydrogen-bonded dimers are formed in 2 via N-H···O interactions due to the 2-pyridone ligand. In 3 the Hpy+ cation is hydrogen bonded to the complex anion and crystal structure is further stabilized by π···π and C-H···O interactions.