Open AccessElectrodialysis of a sodium sulphate solution with experimental bentonite-modified bipolar membranes
Author(s) -
О. А. Козадерова,
K. B. Kim,
П. Е. Белоусов,
А. В. Тимкова,
С. И. Нифталиев
Publication year - 2021
Publication title -
kondensirovannye sredy i mežfaznye granicy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.13
H-Index - 2
eISSN - 2687-0711
pISSN - 1606-867X
DOI - 10.17308/kcmf.2021.23/3670
Subject(s) - electrodialysis , bentonite , membrane , chemistry , ion exchange , sodium , stearic acid , inorganic chemistry , chromatography , sodium tetraphenylborate , nuclear chemistry , chemical engineering , ion , organic chemistry , biochemistry , engineering
The aim of this work is to study the characteristics of the electrodialysis of a sodium sulphate solution with experimental bipolar membranes based on the MA-41 anion exchange membrane and a liquid sulphonated cation-exchanger modified with bentonite clays. The conversion of sodium sulphate was conducted by electrodialysis with bipolar membranes obtained by applying a liquid sulphonated cation-exchanger containing particles of bentonite clay to the MA-41 anion-exchange membrane.To increase the performance of membranes in terms of hydrogen and hydroxyl ions, we carried out organomodifications of bentonite with alkyldimethylbenzylammonium chloride and stearic acid at various concentrations. The bipolar membrane with the addition of bentonite modified with alkyldimethylbenzylammonium chloride (2 wt%) showed a higher performance in terms of H+-ions. The bipolar membrane with bentonite modified with stearic acid (3 wt%) added to its cation-exchangelayer is the most effective in terms of obtaining a flux of OH--ions. It was shown that a combination ofalkyldimethylbenzylammonium chloride (2 wt%) and stearic acid (3 wt%) used to modify bentonite can increase the performance of the bipolar membrane during the conversion of sodium sulphate, both in terms of the acid and alkali.