Influência da acidez do meio sobre a síntese e o comportamento redox do polipirrol | Zendy

M. T. Giacomini | Zendy; Édson Antônio Ticianelli | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Influência da acidez do meio sobre a síntese e o comportamento redox do polipirrol

Author(s) -

M. T. Giacomini,

Édson Antônio Ticianelli

Publication year - 1999

Publication title -

química nova

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.214

H-Index - 73

eISSN - 1678-7064

pISSN - 0100-4042

DOI - 10.1590/s0100-40421999000500002

Subject(s) - redox , aqueous solution , polypyrrole , fourier transform infrared spectroscopy , chemistry , polymer , inorganic chemistry , electrochemistry , polymer chemistry , polymerization , chemical engineering , organic chemistry , electrode , engineering

The influence of acidity on the synthesis and redox behavior of polypyrrole films was studied using galvanostatic and potentiodynamic techniques employing aqueous solutions formed by H2SO4/Na2SO4 , HCl/NaCl and HCl/CsCl. The chemical structure of the films were investigated using the FTIR technique. The polymer behavior as a function of the pH used in the cyclic voltammetric measurements is explained in terms of the mechanism responsible for the charge compensation formed during the polymer chain oxidation. From the FTIR measurements, it is seen that the water nucleophilic attack during the synthesis, does not occur under the experimental conditions employed in this work

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Empowering knowledge with every search

About

About Careers Publisher Partners Contact Us

Learn

FAQs Blog Terms of Use Privacy Policy

About

Learn

Discover

Explore