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Síntese e caracterização de compostos organometálicos de estanho (IV)
Author(s) -
Geraldo Μ. de Lima
Publication year - 1999
Publication title -
química nova
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.214
H-Index - 73
eISSN - 1678-7064
pISSN - 0100-4042
DOI - 10.1590/s0100-40421999000200005
Subject(s) - chemistry , stoichiometry , reaction conditions , stereochemistry , polymer chemistry , organic chemistry , catalysis
Organotin(IV) derivatives containing bulky R groups have been synthesized and characterized. It is discussed how their syntheses depend on the reaction conditions, such as stoichiometry of starting materials, bulkiness of the organo group attached to the Sn centre as well as temperature in which the reaction is carried out. Finally the molecular structure of Sn2Ph6, determined by X-ray diffraction is reviewed

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