Open AccessDeoxydichlorination of aldehydes catalyzed by Diphenyl sulfoxide
Author(s) -
I. A. Gorbunova,
D. A. Shipilovskikh,
С. А. Шипиловских
Publication year - 2021
Publication title -
chimica techno acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.128
H-Index - 1
eISSN - 2411-1414
pISSN - 2409-5613
DOI - 10.15826/chimtech.2021.8.4.08
Subject(s) - sulfoxide , catalysis , oxalyl chloride , reagent , chemistry , dimethyl sulfoxide , organic chemistry , chloride
The diphenyl sulfoxide-catalyzed conversion of aldehydes to 1,1-dichlorides is reported. The reaction proceeds via a sulfurous (IV)-catalysis manifold in which diphenyl sulfoxide turnover is achieved using oxalyl chloride as a consumable reagent.