Open AccessSynthesis and research of polyfunctional silylureas used in electric deposition of tin-indium alloy
Author(s) -
K. Yu. Ivanova,
М. В. Кузьмин,
Л. Г. Рогожина,
A. O. Patianova,
V.L. Semenov,
R. I. Alexandrov
Publication year - 2021
Publication title -
chimica techno acta
Language(s) - English
Resource type - Journals
eISSN - 2411-1414
pISSN - 2409-5613
DOI - 10.15826/chimtech.2021.8.3.05
Subject(s) - isophorone diisocyanate , tin , materials science , alloy , indium , polyurethane , toluene , solvent , hexamethylene diisocyanate , inert gas , chemical engineering , ultimate tensile strength , electrical resistivity and conductivity , inert , isophorone , polymer chemistry , metallurgy , composite material , chemistry , organic chemistry , diamine , electrical engineering , engineering
Polyfunctional silylureas were synthesized by the interaction of 3-aminopropyltriethoxysilane with isocyanates of various structures in an inert aromatic solvent. Commercially available diisocyanates such as isophorone diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate were used as isocyanates. In this case, freshly distilled toluene was used as a solvent. The structures of the obtained compounds were confirmed by the data of IR and NMR1H spectroscopy. Using the synthesized compounds, formulations of compositions for electrodeposition of a tin-indium alloy on a copper wire were developed. The possibility of using silylureas of various structures as effective surfactants used in the electrodeposition of the tin-indium alloy is shown. The operational characteristics of the obtained wire were investigated, including the wire diameter, coating thickness, tensile strength, electrical resistance, and direct current electrical resistivity.