Open AccessEffect of Annealing Temperature on the Li\(^{ + }\) Ionic Conductivity of La\(_{0.67 - x}\)Li\(_{3x}\)TiO\(_{3 }\)
Author(s) -
Le Dinh Trong,
Pham Duy Long,
Nguyễn Năng Định
Publication year - 2009
Publication title -
communications in physics/communications in physics
Language(s) - English
Resource type - Journals
eISSN - 2815-5947
pISSN - 0868-3166
DOI - 10.15625/0868-3166/19/4/6409
Subject(s) - annealing (glass) , materials science , nanocrystalline material , grain boundary , conductivity , ionic conductivity , analytical chemistry (journal) , grain size , adiabatic process , mineralogy , metallurgy , thermodynamics , nanotechnology , electrolyte , microstructure , chemistry , electrode , chromatography , physics
Perovskite La0.67-xLi3xTiO3 with x = 0.10, 0.11, 0.12 and 0.13 were firstly annealed at 800 oC then treated by reactive milling, followed by post-annealing at temperatures from 1100 to 1200oC. The crystalline structure of grain and grain-boundary were characterized by XRD and SEM. The impedance measurements showed that nanocrystalline La0.67-xLi3xTiO3 after being annealed at 1150 oC possessed a grain conductivity as high as 1.3×10-3 S.cm-1. The grain-boundary conductivity was enhanced one order in magnitude after annealing at temperature higher 1100oC and consists of 5.8×10-5 S.cm-1. The results have also showed the limitation of the adiabatic thermal treatment for the improvement of the grain-boundary conductivity and suggested the way to overcome the limitation by rapidly cooling the samples from the high temperature to room temperature.