Open AccessEntropy Scaling for Viscosity of Pure Lennard-Jones Fluids and Their Binary Mixtures
Author(s) -
The Hung Nguyen,
Samy Khennache,
Guillaume Galliéro,
Tuong Vi Tran,
Luc Tuong,
Phuc Nguyen,
Hai Hoang,
Ho Khac Hieu
Publication year - 2022
Publication title -
communications in physics/communications in physics
Language(s) - English
Resource type - Journals
eISSN - 2815-5947
pISSN - 0868-3166
DOI - 10.15625/0868-3166/16345
Subject(s) - thermodynamics , viscosity , scaling , materials science , binary number , entropy (arrow of time) , statistical physics , physics , mathematics , geometry , arithmetic
In this work, entropy scaling approaches for viscosity of pure Lennard-Jones (LJ) fluids and their mixtures have been investigated. To do so, we have employed reliable viscosity database available in literature for the pure LJ fluids, and performed the molecular dynamics simulation to generate viscosity database over a wide range of thermodynamic condition for the LJ mixture fluids. It has shown that for the pure LJ fluid, the entropy scaling approaches using the macroscopic properties for the reduction of viscosity yield noticeably better collapse of data than the one using the zero-density viscosity in the dense fluid region. In addition, we have developed viscosity correlations based on these approaches. It has been obtained that the correlations of macroscopic properties approaches predict the pure LJ fluid viscosity with average absolute deviation of around 4% more coming from the low-density states, whereas it is of around 8.50% more coming from the dense states for the other one. Finally, the viscosity correlations have been applied to the LJ mixtures. Interestingly, the correlations of macroscopic properties approaches are able to provide good estimations for all mixtures studied. However, it deteriorates for the viscosity of dense mixtures when the other employed.