Open AccessQuantum-Chemical Research of Fluoro Containing Hydrocarbons, That Have Fire Extinguishing Effect
Author(s) -
V. V. Kukueva
Publication year - 2015
Publication title -
fìzika ì hìmìâ tverdogo tìla
Language(s) - English
Resource type - Journals
eISSN - 2309-8589
pISSN - 1729-4428
DOI - 10.15330/pcss.16.3.511-514
Subject(s) - quantum chemical , molecule , fluorine , chemical reaction , chemistry , materials science , computational chemistry , photochemistry , chemical physics , chemical engineering , organic chemistry , engineering
Through quantum-chemical calculations, a study was conducted to find the probable products of the destruction of molecules of extinguishing agents. The formation of atomic fluorine and trifluoromethane radical has been shown to contribute to the retardation of elementary reactions in the flame. It has been shown that active inhibitory components are more easily dissociated from the silica surface than in the case of bulk molecules.