Influence of External Pressures of Different Symmetry on the Phase Transitions and Thermodynamic of the RbHSO4 Ferroelectrics | Zendy

І. Р. Зачек | Zendy; M.C. Karkuljevska | Zendy; A. S. Vdovych | Zendy; R. R. Levitsky | Zendy

Open Access

Influence of External Pressures of Different Symmetry on the Phase Transitions and Thermodynamic of the RbHSO4 Ferroelectrics

Author(s) -

І. Р. Зачек,

M.C. Karkuljevska,

A. S. Vdovych,

R. R. Levitsky

Publication year - 2015

Publication title -

physics and chemistry of solid state

Language(s) - English

Resource type - Journals

eISSN - 2309-8589

pISSN - 1729-4428

DOI - 10.15330/pcss.16.2.276-283

Subject(s) - piezoelectricity , phase transition , condensed matter physics , hydrostatic pressure , dielectric , materials science , polarization (electrochemistry) , dielectric permittivity , tensor (intrinsic definition) , permittivity , hydrostatic equilibrium , crystal (programming language) , coupling (piping) , phase (matter) , symmetry (geometry) , thermodynamics , physics , chemistry , mathematics , composite material , geometry , quantum mechanics , optoelectronics , computer science , programming language

We use the four-sublattice model of the RbHSO4 crystal modified by taking into account the piezoelectric coupling to the strains , . Within the mean field approximation we calculate the components of the polarization vector and static dielectric permittivity tensor of mechanically clamped and free crystals, as well as their piezoelectric characteristics. We study the influence of hydrostatic pressure and uniaxial stresses on the phase transition and physical characteristics of the crystal. A good quantitative description of the experimental data is obtained.

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