Open AccessDETERMINING THE ROLE OF INDIVIDUAL FLY ASH PARTICLES IN INFLUENCING THE VARIATION IN THE OVERALL PHYSICAL, MORPHOLOGICAL, AND CHEMICAL PROPERTIES OF FLY ASH
Author(s) -
Usman Haider,
Z. Bittnar,
Lubomír Kopecký,
Vít Šmilauer,
Jaroslav Pokorný,
Martina Záleská,
Zdeněk Prošek,
Vladimír Hrbek
Publication year - 2016
Publication title -
acta polytechnica
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.207
H-Index - 15
eISSN - 1805-2363
pISSN - 1210-2709
DOI - 10.14311/ap.2016.56.0265
Subject(s) - fly ash , materials science , cementitious , mineralogy , raw material , porosity , calcite , particle (ecology) , metallurgy , silicate , cement , composite material , chemical engineering , geology , chemistry , oceanography , organic chemistry , engineering
The properties of fly ashes vary because of the differences in the properties of their individual particles, and the determination of variation in these properties is of interest to the industries which use pulverized raw fly ash in applications, such as in cementitious materials and in the recovery of certain rare elements from raw fly ash. To investigate the differences in individual particles, four pulverized raw fly ashes from thermal power plants of the Czech Republic were used in this research. It was observed from FE-SEM that all four fly ashes consist of glassy hollow spherical, solid spherical, porous spherical, bright spherical, porous slaggy and compact slaggy particles. Box and whisker diagrams were plotted from the data of EDX individual particle analyses, which showed that the data of percentages for the Si, Al, and Fe elements is more scattered as compared to other elements. It was further observed from ternary phase diagrams and pseudo coloured images, that nature of fly ash particles changes from alumino silicate glassy to alumino silicate calcite metallic to pure ferro-metallic,where glassy particles showed high percentages and pure calcite particles were absent in fly ashes. Furthermore, a comparison between the XRF, the EDX total area analyses, showed that the EDX individual particle analysis gives more realistic and reliable data with median, mean, and the standard deviation for percentages of each element present in the fly ashes.