Open AccessMonoorganosilicon(IV) Complexes of 2-Aminocyclopentene-1-carbodithioic Acid and its N-/S-Alkyl Derivatives: Synthesis and Characterization
Author(s) -
Ramavtar Sharma,
Malti Sharma,
Yashpal Singh
Publication year - 2021
Publication title -
asian journal of chemistry/asian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.145
H-Index - 34
eISSN - 0975-427X
pISSN - 0970-7077
DOI - 10.14233/ajchem.2021.23538
Subject(s) - chemistry , alkyl , moiety , nitrogen atom , ligand (biochemistry) , sulfur , elemental analysis , chloride , atom (system on chip) , medicinal chemistry , nitrogen , sodium salt , salt (chemistry) , silicon , molar ratio , carbon 13 nmr , stereochemistry , inorganic chemistry , organic chemistry , catalysis , biochemistry , receptor , computer science , embedded system
2-Aminocyclopentene-1-carbodithioic acid (ACDA) and its N-/S-alkyl derivatives of methylsilicon(IV)chloride have been synthesized by the reactions of MeSiCl3 with sodium salt of ACDA and itsN-/S-alkyl derivatives in 1:1 and 1:2 molar ratios. All these complexes have been characterized byelemental analysis, molecular weight measurements and spectroscopic (IR, 1H and 13C NMR) studies.The central silicon atom is coordinated to two sulphur atoms or one sulphur atom and one nitrogenatom of the ligand moiety in all of these derivatives, resulting in five and six coordination.