Open AccessCharge Transfer Interactions of p-Azoxyanisole Complexes for Electrooptical Activity
Author(s) -
Ch. Ravi Kumar,
S. Deepthi,
Anjali Jha
Publication year - 2020
Publication title -
asian journal of chemistry/asian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.145
H-Index - 34
eISSN - 0975-427X
pISSN - 0970-7077
DOI - 10.14233/ajchem.2020.22624
Subject(s) - chemistry , supramolecular chemistry , molecule , raman spectroscopy , electron transfer , charge (physics) , chemical physics , metal , electron , spectral line , molecular physics , photochemistry , optics , organic chemistry , physics , quantum mechanics , astronomy
In particular interactions due to organic-inorganic molecules results self assembled structures organizesupramolecular structures for molecular, electronic and electrooptical properties. Supramolecularstructures originated are complexes with organic (p-azoxyanisole) molecule, synthesized with metalnanoparticles (iron, copper and aluminium.) Spectroscopic studies interpret infrared spectra withwavenumbers of characteristic bands in assigned regions; wavenumbers with reduced intensity inRaman spectra attribute metal-organic framework with charge transfer. Designed frame work withdense participation of carriers interpret electron correlation and exchange interaction specifyingmolecular, electronic and electrooptical properties with Gaussian package using electron density method.Deterministic procedure attribute vital role of charge transfer interactions responsible in formation ofcomplex with improvement in properties responsible for electrooptical activity.