Open AccessSynthesis, Characterization and DNA Binding Studies of N,N′-bis(2-Hydroxy-5-methylbenzylidene)- 2-hydroxy-propane-1,3-diamine Copper(II) and Nickel(II) Complexes
Author(s) -
Ramina,
Rajkumar Bhubon Singh,
Oinam U-wang,
Thiyam Ramsing Singh,
T. Tiakaba Jamir
Publication year - 2020
Publication title -
asian journal of chemistry/asian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.145
H-Index - 34
eISSN - 0975-427X
pISSN - 0970-7077
DOI - 10.14233/ajchem.2020.22615
Subject(s) - chemistry , diamine , nickel , copper , schiff base , crystallography , propane , diffractometer , cyclic voltammetry , ethylene diamine , metal , transition metal , crystal structure , stereochemistry , polymer chemistry , electrochemistry , nuclear chemistry , organic chemistry , electrode , catalysis
Two new Schiff base transition metal complexes [Cu(HL)]2.CH3CH2OH (1) and [Ni(HL)] (2) (L =N,N′-bis(2-hydroxy-5-methyl-benzylidene)-2-hydroxy-propane-1,3-diamine) were synthesized andcharacterized by different physico-chemical and spectroscopic techniques. Structure of complex 1was determined by single crystal X-ray diffractometer. Both the complexes have distorted squareplanar geometry. The DNA binding study of two complexes was performed via electronic absorption,cyclic voltammetry, photoluminescence, and viscosity methods and found to be intercalative mode ofbinding.