Open AccessMicro-structural, Morphological and Optical Properties of Pure and Metal (Mn & Mg) Doped ZnO Thin Films by Low Cost SILAR Method
Author(s) -
K. Radhi Devi,
G. Selvan,
M. Karunakaran,
K. Kasirajan
Publication year - 2019
Publication title -
asian journal of chemistry/asian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.145
H-Index - 34
eISSN - 0975-427X
pISSN - 0970-7077
DOI - 10.14233/ajchem.2019.21834
Subject(s) - crystallite , scanning electron microscope , fourier transform infrared spectroscopy , zinc , doping , chemistry , thin film , analytical chemistry (journal) , metal , band gap , spectroscopy , metal ions in aqueous solution , materials science , chemical engineering , crystallography , nanotechnology , optoelectronics , organic chemistry , composite material , physics , quantum mechanics , engineering
Pure and metals (Mn & Mg) doped zinc oxide (ZnO, ZnO/Mn and ZnO/Mg) thin films have been successfully grown onto a glass substrates by low cost SILAR method. The structural, morphological, compositional, functional group and optical properties of the prepared films were studied using X-ray diffraction, scanning electron microscope and EDAX, FTIR and UV-visible spectrophotometer, respectively. The structure of the films were found to be hexagonal with polycrystalline in nature with preferential orientation along (002) plane. From Fourier Transform Infrared spectroscopy, the presence of functional groups and its corresponding molecular vibrations were assessed. In UV-visible spectroscopy, the obtained direct optical band gap values 3.46, 3.56 and 3.7 eV for pure, Mn and Mg doped ZnO thin films, respectively. Morphological results showed that the remarkable changes in morphology due to the effect of metal doping. EDAX studies showed that the presence of zinc and oxygen content and also a doping metal ions.