Open AccessPhysico-Chemical Analysis on Some Polymers in Aqueous Surfactant Solution at Different Temperatures: Acoustical, UV and FTIR Studies
Author(s) -
N. Chithralekha,
Arunkumar Panneerselvam
Publication year - 2019
Publication title -
asian journal of chemistry/asian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.145
H-Index - 34
eISSN - 0975-427X
pISSN - 0970-7077
DOI - 10.14233/ajchem.2019.21771
Subject(s) - chemistry , vinyl alcohol , aqueous solution , solvation , polymer , critical micelle concentration , micelle , pulmonary surfactant , thermodynamics of micellization , viscosity , fourier transform infrared spectroscopy , ethylene glycol , analytical chemistry (journal) , chemical engineering , polymer chemistry , thermodynamics , molecule , organic chemistry , biochemistry , physics , engineering
The ultrasonic velocity, density and viscosity in mixtures of sorbitan sesquioleate and poly(vinyl pyrrolidone) (PVP), poly(vinyl alcohol) (PVA) and poly(ethylene glycol) (PEG) in different concentration ranges are measured at different temperatures (303, 313 and 323 K). From the experimental data, other related acoustical parameters such as adiabatic compressibility (β), intermolecular free length (Lf), internal pressure (πi), Rao’s constant (Ra), relaxation time (τ), acoustical impedance (Za), absorption coefficient (α/f2), free volume (Vf), cohesive energy (CE) and solvation number (Sn) have been evaluated. In aqueous solutions, surfactant molecule starts to aggregate and form micelle in concentration called as critical micelle concentration (CMC). It is one of the most important physical parameters of the surfactants. These results were interpreted in terms of surfactantpolymer complex reactions. The combinations of surfactant with polymers improve the desired properties of the product and the formation of complex was confirmed by UV and FTIR studies.