Open AccessA Mixture of Iodide Ion and Gum Exudates of Eucalyptus globules as Green Inhibitor for Dissolution Control of Mild Steel in 1 N HCl Medium
Author(s) -
S. Dheenadhayalan,
R. Roja,
V. Nijarubini,
J. Mallika
Publication year - 2019
Publication title -
asian journal of chemistry/asian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.145
H-Index - 34
eISSN - 0975-427X
pISSN - 0970-7077
DOI - 10.14233/ajchem.2019.21639
Subject(s) - dissolution , chemistry , iodide , physisorption , nuclear chemistry , tafel equation , adsorption , electrochemistry , inorganic chemistry , electrode , organic chemistry
The mild steel dissolution in 1 N HCl medium was monitored in the presence and absence of gum exudates of Eucalyptus globles (GEG) using quantitative gravimetric method at 303-323 K. The synergistic influence of iodide ions with GEG on the dissolution of mild steel was also studied at 303-323 K. The impedance (Rct and Cdl) and polarization (ba, bc, icorr, Ecorr) parameters were obtained from electrochemical methods for the optimum concentration of GEG and GEG + I–. The dissolution of mild steel decreases with increase in the concentration of GEG and GEG + I– at 30 °C. But their inhibition ability of tested inhibitor system for dissolution control of mild steel decreases with increase in temperature but rate of dissolution of mild steel is comparatively less in the case of GEG + I–. Adsorption of GEG on mild steel obeys Langmuir’s isotherm and supports physisorption process. Tafel’s parameters confirm the mixed nature of the studied inhibitor.