Open AccessFTIR time series of stratospheric NO2 over Hefei, China, and comparisons with OMI and GEOS-Chem model data
Author(s) -
Hao Yin,
Youwen Sun,
Cheng Liu,
Lin Zhang,
Xiao Lu,
Wei Wang,
Changgong Shan,
Qihou Hu,
Yuan Tian,
Chengxin Zhang,
Wenjing Su,
Huifang Zhang,
Mathias Palm,
Justus Notholt,
Jianguo Liu
Publication year - 2019
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.27.0a1225
Subject(s) - fourier transform infrared spectroscopy , satellite , atmospheric sciences , environmental science , ozone monitoring instrument , atmosphere (unit) , fourier transform , stratosphere , physics , meteorology , climatology , analytical chemistry (journal) , chemistry , troposphere , optics , geology , environmental chemistry , astronomy , quantum mechanics
We present the trend and seasonal variability of stratospheric NO 2 column for the first time over the polluted atmosphere at Hefei, China, retrieved using Fourier transform infrared spectroscopy (FTIR) between 2015 and 2018. The FTIR observed stratospheric NO 2 columns over Hefei show a peak in June and reach a minimum in January. The mean stratospheric NO 2 column concentration in June is (3.49 ± 0.25) × 10 15 molecules*cm -2 , and is 39.20% ± 8.95% higher than that in January with a mean value of (2.51 ± 0.21) × 10 15 molecules*cm -2 . We find a negative trend of (-0.34 ± 0.05) %/yr in the FTIR observations of stratospheric NO 2 column. The FTIR data are compared to the satellite OMI observations to assess the new data set quality and also applied to evaluate the GEOS-Chem model simulations. We find in general the OMI observations and GEOS-Chem model results are in good agreement with the coincident FTIR data, and they all show similar seasonal cycles with strong correlation coefficients of 0.84-0.86. The annual average OMI minus FTIR difference is (1.48 ± 5.33) × 10 14 molecules*cm -2 (4.82% ± 17.37%), and average GEOS-Chem minus FTIR difference is (2.36 ± 2.33) × 10 14 molecules*cm -2 (7.66% ± 7.49%). Their maximum differences occur in April and May with mean differences of 12-16%. We also found negative trends in the stratospheric NO 2 column over Hefei for 2015-2018 with both OMI observations (-0.91 ± 0.09%/yr) and GEOS-Chem model results (-0.31 ± 0.05%/yr), demonstrating some consistency among them.