Open AccessDynamic high pressure induced strong and weak hydrogen bonds enhanced by pre-resonance stimulated Raman scattering in liquid water
Author(s) -
Shenghan Wang,
WenHui Fang,
Fabing Li,
Nan Gong,
Zhanlong Li,
Zuowei Li,
Chenglin Sun,
Zhiwei Men
Publication year - 2017
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.25.031670
Subject(s) - raman scattering , raman spectroscopy , resonance (particle physics) , materials science , laser , optics , hydrogen , scattering , spectral line , atomic physics , hydrogen bond , atmospheric pressure , analytical chemistry (journal) , nuclear magnetic resonance , chemistry , physics , molecule , chromatography , astronomy , meteorology , organic chemistry
355 nm pulsed laser is employed to excite pre-resonance forward stimulated Raman scattering (FSRS) of liquid water at ambient temperature. Due to the shockwave induced dynamic high pressure, the obtained Raman spectra begin to exhibit double peaks distribution at 3318 and 3373 cm -1 with the input energy of 17 mJ,which correspond with OH stretching vibration with strong and weak hydrogen (H) bonds. With laser energy rising from 17 to 27 mJ, the Stokes line at 3318 cm -1 shifts to 3255 and 3230 cm -1 because of the high pressure being enlarged. When the energy is up to 32 mJ, only 3373 cm -1 peak exists. The strong and weak H bond exhibit quite different energy dependent behaviors.