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Synthesis and luminescence properties of Ba_3Lu(PO_4)_3:Sm^3+ phosphor for white light-emitting diodes
Author(s) -
Zaifa Yang,
Denghui Xu,
Jiayue Sun
Publication year - 2017
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.25.00a391
Subject(s) - phosphor , photoluminescence , materials science , luminescence , dopant , light emitting diode , analytical chemistry (journal) , emission spectrum , emission intensity , photoluminescence excitation , radiative transfer , optoelectronics , optics , color temperature , spectral line , doping , chemistry , physics , chromatography , astronomy
A series of Ba 3 Lu(PO 4 ) 3 :Sm 3+ phosphors were prepared by traditional high temperature solid-state reaction methods. The site-preferred occupancy of Sm 3+ in Ba 3 Lu(PO 4 ) 3 and the luminescence properties of Ba 3 Lu(PO 4 ) 3 :Sm 3+ were studied combined with X-ray diffraction, photoluminescence excitation (PLE) spectra, and emission (PL) spectra as well as temperature-dependent PL and decay curves. The PL intensity is improved with increasing Sm 3+ content and the optimal dopant content is 0.05. The temperature-dependent PL spectra indicate that the emission intensity decreases with the temperature because of the enhancement of the non-radiative transition. The results indicate that these reddish-orange emitting phosphors could be for potential applications in w-LEDs.

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