Open AccessA novel setup for femtosecond pump-repump-probe IR spectroscopy with few cycle CEP stable pulses
Author(s) -
Maximilian Bradler,
Jasper C. Werhahn,
Daniel Hutzler,
Simon Fuhrmann,
Rupert Heider,
Eberhard Riedle,
Hristo Iglev,
Reinhard Kienberger
Publication year - 2013
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.21.020145
Subject(s) - femtosecond , optics , materials science , nanosecond , spectroscopy , temporal resolution , laser , physics , quantum mechanics
We present a three-color mid-IR setup for vibrational pump-repump-probe experiments with a temporal resolution well below 100 fs and a freely selectable spectral resolution of 20 to 360 cm(-1) for the pump and repump. The usable probe range without optical realignment is 900 cm(-1). The experimental design employed is greatly simplified compared to the widely used setups, highly robust and includes a novel means for generation of tunable few-cycle pulses with stable carrier-envelope phase. A Ti:sapphire pump system operating with 1 kHz and a modest 150 fs pulse duration supplies the total pump energy of just 0.6 mJ. The good signal-to-noise ratio of the setup allows the determination of spectrally resolved transient probe changes smaller than 6·10(-5) OD at 130 time delays in just 45 minutes. The performance of the spectrometer is demonstrated with transient IR spectra and decay curves of HDO molecules in lithium nitrate trihydrate and ice and a first all MIR pump-repump-probe measurement.