Open AccessPr^3+-doped heavy metal germanium tellurite glasses for irradiative light source in minimally invasive photodynamic therapy surgery
Author(s) -
Jiaxin Yang,
B. J. Chen,
Edwin Yue-Bun Pun,
Bin Zhai,
Hai Lin
Publication year - 2013
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.21.001030
Subject(s) - germanium , fluorescence , photodynamic therapy , doping , materials science , excitation , wavelength , quantum yield , optics , luminescence , excitation wavelength , analytical chemistry (journal) , optoelectronics , chemistry , physics , organic chemistry , chromatography , quantum mechanics , silicon
Pr3+-doped medium-low phonon energy heavy metal germanium tellurite (NZPGT) glasses have been fabricated and the intense multi-peak red fluorescence emissions of Pr3+ are exhibited. Judd-Ofelt parameters Ω2 = 3.14 × 10(-20)cm(2), Ω4 = 10.67 × 10(-20)cm(2) and Ω6 = 3.95 × 10(-20)cm(2) indicate a high asymmetrical and covalent environment in the optical glasses. The spontaneous emission probabilities A(ij) corresponding to the 1D2→3H4, 3P0→3H6, and 3P0→3F2 transitions are derived to be 1859.6, 6270.1 and 17276.3s(-1), respectively, and the relevant stimulated emission cross-sections σ(em) are 5.20 × 10(-21), 14.14 × 10(-21) and 126.77 × 10(-21)cm(2), confirming that the effectiveness of the red luminescence in Pr3+-doped NZPGT glasses. Under the commercial blue LED excitation, the radiant flux and the quantum yield for the red fluorescence of Pr3+ are solved to be 219μW and 11.80%, respectively. 85.24% photons of the fluorescence in the visible region are demonstrated to be located in 600-720nm wavelength range, which matches the excitation band of the most photosensitizers (PS), holding great promise for photodynamic therapy (PDT) treatment and clinical trials.