Open AccessAnalysis on fluorescence intensity reverse photonic phenomenon between red and green fluorescence of oxyfluoride nanophase vitroceramics
Author(s) -
Xiaobo Chen,
Zengfu Song,
Junjie Zhang,
Lili Hu,
Liping Wen,
Ce Wang,
Li Song
Publication year - 2007
Publication title -
optics express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.394
H-Index - 271
ISSN - 1094-4087
DOI - 10.1364/oe.15.013421
Subject(s) - fluorescence , excited state , optics , materials science , photonics , relaxation (psychology) , intensity (physics) , ion , atomic physics , physics , psychology , social psychology , quantum mechanics
An interesting fluorescence intensity reverse photonic phenomenon between red and green fluorescence is investigated. The dynamic range Sigma of intensity reverse between red and green fluorescence of Er(0.5)Yb(3):FOV oxyfluoride nanophase vitroceramics, when excited by 378.5nm and 522.5nm light respectively, is about 4.32x10(2). It is calculated that the phonon-assistant energy transfer rate of the electric multi-dipole interaction of {(4)G(11/2)(Er(3+))?(4)F(9/2)(Er(3+)), (2)F(7/2)(Yb(3+))?(2)F(5/2)(Yb(3+))} energy transfer of Er(0.5)Yb(3):FOV is around 1.380x10(8)s(-1), which is much larger than the relative multiphonon nonradiative relaxation rates 3.20x10(5)s(-1). That energy transfer rate for general material with same rare earth ion's concentration is about 1.194x10(5)s(-1). These are the reason to emerge the unusual intensity reverse phenomenon in Er(0.5)Yb(3):FOV.