How clean is the solvent you use to clean your optics? A vibrational sum-frequency-generation study

Solvents for cleaning optics often come into contact with plastic and/or rubber during storage and transfer. To explore the effects that exposure to these materials can have on solvents, we used vibrational sum-frequency-generation spectroscopy to study a silica optic following cleaning with solvents that had come into contact with either low-density polyethylene, high-density polyethylene, or rubber. Our studies show that even brief contact of acetone, methanol, or isopropanol with plastic or rubber can cause otherwise pure solvents to leave a persistent residue.