H-bonded Chains and Networks: A Recurring Feature in the Solid State Structures of Manganese (III) Carboxylate Schiff Base Complexes | Zendy

B.S. Arun Sasi | Zendy; S Swathy | Zendy; V. S. Thampidas | Zendy; Pike D Robert | Zendy

Open Access

H-bonded Chains and Networks: A Recurring Feature in the Solid State Structures of Manganese (III) Carboxylate Schiff Base Complexes

Author(s) -

B.S. Arun Sasi,

S Swathy,

V. S. Thampidas,

Pike D Robert

Publication year - 2013

Publication title -

mapana journal of sciences

Language(s) - English

Resource type - Journals

ISSN - 0975-3303

DOI - 10.12723/mjs.25.2

Subject(s) - manganese , schiff base , octahedron , crystallography , carboxylate , solid state , jahn–teller effect , chemistry , crystal structure , stereochemistry , ion , organic chemistry

Two new manganese(III) Schiff base complexes, [Mn(salen)(m-NO2-C6H4CO2)(H2O)] (1) and [Mn(msalen) (p-OH-C6H4CO2)(H2O)] (2), where H2salen = N,N'-bis(salicylidene)-1,2-diaminoethane, H2msalen = N,N'-bis (3-methoxysalicylidene)-1,2-diaminoethane were synthesized from the manganese (II) carboxylates. Single crystal X-ray diffraction studies show that the Jahn-Teller distorted octahedral complexes are stabilized by H-bonded chains and networks in the solid state.

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