Synthesis of 2-(Substituted Methyl)-3,4-Disubstituted Pyrroles and Their Conversion into the Corresponding Porphyrins | Zendy

Hideki Kinoshita | Zendy; Shingo Tanaka | Zendy; Natsu Nishimori | Zendy; Hiroshi Dejima | Zendy; Katsuhiko Inomata | Zendy

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Synthesis of 2-(Substituted Methyl)-3,4-Disubstituted Pyrroles and Their Conversion into the Corresponding Porphyrins

Author(s) -

Hideki Kinoshita,

Shingo Tanaka,

Natsu Nishimori,

Hiroshi Dejima,

Katsuhiko Inomata

Publication year - 1992

Publication title -

bulletin of the chemical society of japan

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.145

H-Index - 99

eISSN - 1348-0634

pISSN - 0009-2673

DOI - 10.1246/bcsj.65.2660

Subject(s) - chemistry , hydroxymethyl , pyrrole , nucleophile , base (topology) , organic chemistry , medicinal chemistry , regioselectivity , catalysis , mathematical analysis , mathematics

2-Hydroxymethyl-1-methylsulfonyl-3,4-disubstituted pyrroles and 2-hydroxymethyl-3,4-disubstituted pyrroles were effectively converted into the corresponding 2-(substituted methyl)pyrrole derivatives by the reaction with various nucleophiles in the presence of base. These products were further transformed to the corresponding porphyrins regioselectively under almost neutral or basic conditions

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