Open AccessImpact of Carbon Dioxide on the Activity and Selectivity of Supported Palladium Catalysts for Carbon Monoxide Hydrogenation
Author(s) -
Г. В. Філоненко
Publication year - 1996
Publication title -
adsorption science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.682
H-Index - 36
eISSN - 2048-4038
pISSN - 0263-6174
DOI - 10.1177/026361749601400502
Subject(s) - chemistry , palladium , carbon monoxide , catalysis , selectivity , carbon dioxide , inorganic chemistry , methanol , cubic zirconia , electrochemical reduction of carbon dioxide , oxygen , compounds of carbon , organic chemistry , chemical reaction , ceramic
The introduction of 1.5 vol.% carbon dioxide into the reaction mixture (CO/H 2 = 1:2) is shown to accelerate the rate of formation of methanol and the selectivity towards oxygen-containing products over palladium catalysts supported on oxides of various chemical natures. The maximum degree of impact of CO 2 was observed over palladium supported on magnesia and zirconia.