Open AccessGas Adsorption Operations: Equilibrium, Kinetics, Column Dynamics and Design
Author(s) -
Shivaji Sircar,
Alan L. Myers
Publication year - 1985
Publication title -
adsorption science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.682
H-Index - 36
eISSN - 2048-4038
pISSN - 0263-6174
DOI - 10.1177/026361748500200202
Subject(s) - adsorption , chemistry , pressure swing adsorption , thermodynamics , mass transfer , kinetics , kinetic energy , chromatography , physics , quantum mechanics
Separation and purification of gaseous mixtures by adsorption has become a valuable tool in the chemical industry. Gas adsorption operations require information on both equilibrium and kinetics. Analytical equations are available to describe the adsorption of pure gases; mixture equilibria can be predicted by thermodynamic methods. Kinetic data suitable for column design can be expressed in terms of overall mass transfer coefficients. Design of columns for thermal swing adsorption (TSA) or pressure swing adsorption (PSA) processes requires the simultaneous solution of the partial differential equations for the material, energy and momentum balances describing the dynamics of adsorption in columns. Numerical solutions are usually required, but some useful analytical solutions are available for special cases.