Open AccessMixing State of Submicrometer Sea Spray Particles Enriched by Insoluble Species in Bubble-Bursting Experiments
Author(s) -
Ji Yeon Park,
Sang-Hyun Lim,
Kihong Park
Publication year - 2014
Publication title -
journal of atmospheric and oceanic technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.774
H-Index - 124
eISSN - 1520-0426
pISSN - 0739-0572
DOI - 10.1175/jtech-d-13-00086.1
Subject(s) - seawater , artificial seawater , sea salt , sea spray , environmental chemistry , chemistry , mineralogy , oceanography , geology , aerosol , organic chemistry
Measurements of size distribution, hygroscopicity, and volatility of submicrometer sea spray particles produced by the bubble busting of artificial and natural seawater were conducted to determine their mixing state and volume fractions of hygroscopic and nonhygroscopic species or volatile and nonvolatile species. The particles sprayed from artificial seawater having insoluble silica particles were found to be an external mixture of two groups of particles having hygroscopic growth factors (HGFs) of 1.33 (an internal mixture of nonhygroscopic silica particles and hygroscopic salt species) and 1.68 (a similar mixture having more salt species) when the mass ratio of insoluble particles to dissolved salts was higher than 2. For sea spray particles from natural seawater, the external mixing was not significantly observed because of a high concentration of dissolved salts. The HGFs of sea spray particles (80–140 nm) from natural seawater were in the range of 1.70–1.76, which were lower than from pure artificial seawater (1.87), and the HGFs had no change before and after membrane filtration of seawater, suggesting that the sea spray particles from natural seawater contained a significant amount of nonhygroscopic dissolved organic matter in addition to hygroscopic salt species. The volume fraction of the nonhygroscopic species ranged from 20% to 29%, and the highest value was observed for seawater samples from the site where strong biological activity occurred, suggesting that biological materials played an important role in the formation of nonhygroscopic organic matter. Volatility measurements also identified the existence of volatile organic species in single particles from natural seawater, with the volume fraction of volatile species evaporated at 100°C being 4%–5%.