Open AccessSelf-doped carrier as a performance limiting factor of perovskite solar cells: study on tandem-junction cells with SCAPS
Author(s) -
Md. Sazzadur Rahman,
M. F. Rahman,
Al Jaber,
Suman Miah
Publication year - 2021
Publication title -
indonesian journal of electrical engineering and computer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.241
H-Index - 17
eISSN - 2502-4760
pISSN - 2502-4752
DOI - 10.11591/ijeecs.v24.i1.pp81-89
Subject(s) - materials science , solar cell , doping , perovskite (structure) , perovskite solar cell , carrier lifetime , optoelectronics , tandem , energy conversion efficiency , optics , silicon , chemistry , composite material , physics , crystallography
Doping concentration of the absorber layer plays a vital role in the performance of perovskite solar cells, because not only it has a direct impact on the collection efficiency of the photo generated carriers, but it can also be considered as an indicator of the film quality and aging process for so-called self-doped (unintentionally doped) perovskite absorbers, where the carriers are induced from structural imperfections. To observe its influence on the efficiency of perovskite solar cell, a two-junction solar cell structure MAPbBr3/MAPbI3 is analyzed in this study, employing a novel optoelectrical simulation approach with finite-difference time-domain (FDTD) analysis and solar cell capacitance simulation (SCAPS) program. It is found that, the efficiency of the tandem cell falls from ∼22% to ∼12% as front-cell absorber film degrades from single-crystal quality with low self-doped carrier concentration of the order of 1010cm−3 , to degraded film quality with very high carrier concentration of the order of 1018cm−3 . In contrast, the self-doped carrier concentration of the back-cell absorber illustrates less impact on the efficiency of the cell, especially for thicker front-cell absorber. Thus, this case study gives a simpler but novel insight into the long-term stability of the efficiency of high-performance perovskite solar cells establishing a link between the solar cell performance and the self-doped carrier concentration (doping concentration) of the absorber film.