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In this work we have studied the effect of 1 M bis(trifluoromethanesulfonyl)imide metallic salts in acetonitrile (1 M MeTFSI, where Me = Li, Na, K, Cs or Mg) as an electrolyte for electrochemical capacitors (ECs), using computational quantum mechanical modelling, Raman analysis, cyclic voltammetry, electrochemical impedance spectroscopy and constant power methods. Also, the ionic conductivities of 1 M MeTFSI in AN have been measured and discussed. The ECs based on the 1 M KTFSI in AN electrolyte deliver the higher power density and energy density compared to other MeTFSI based electrolytes and showing excellent characteristics applicable in high energy and power EC devices.

journal of the electrochemical society

Bis(trifluoromethanesulfonyl)imide Metallic Salts Based Electrolytes for Electrochemical Capacitor Application: Theoretical vs Experimental Performance