Open AccessA Deep Eutectic Solvent as Leaching Agent and Electrolytic Bath for Silver Recovery from Spent Silver Oxide Batteries
Author(s) -
W. Sánchez-Ortiz,
J. Aldana-González,
Tu Le Manh,
M. Romero-Romo,
I. Mejía-Caballero,
Marı́a Teresa Ramı́rez-Silva,
E.M. Arce-Estrada,
Violeta Múgica-Álvarez,
Manuel PalomarPardavé
Publication year - 2021
Publication title -
journal of the electrochemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.258
H-Index - 271
eISSN - 1945-7111
pISSN - 0013-4651
DOI - 10.1149/1945-7111/abdb01
Subject(s) - leaching (pedology) , oxide , scanning electron microscope , nucleation , electrochemistry , deep eutectic solvent , cathode , materials science , graphite , eutectic system , metal , electrolyte , inorganic chemistry , glassy carbon , silver oxide , chemistry , chemical engineering , metallurgy , electrode , microstructure , cyclic voltammetry , composite material , environmental science , organic chemistry , soil science , engineering , soil water
It is shown for the first time that the deep eutectic solvent, DES, formed by acetylcholine chloride and urea can be successfully used for Ag recovery from the cathode powder of spent silver oxide batteries. This DES performs two important functions namely, as selective leaching liquor to extract Ag(I) ions from the remaining Ag 2 O, leaving intact the metallic Ag in the solid phase, and as electrolytic bath for silver electrodeposition onto a glassy carbon electrode or graphite. Using potentiodynamic and potentiostatic electrochemical measurements, it was possible to quantify both: the Ag(I) leaching rate and the concentration of Ag(I) ions leached after 24 h. From this value, it was possible to estimate that about 7% of the original mass of the cathode powder corresponds to Ag 2 O and the rest to metallic Ag. Moreover, from potentiostatic current density transients, recorded during Ag electrodeposition, it was shown, for the first time in this DES, that this process occurs via multiple 3D nucleation with diffusion-controlled growth and valuable practical information i.e. the diffusion coefficient of Ag(I) ions in this media was quantified. From scanning electron microscopy images and energy-dispersive X-ray spectroscopy, the morphology and composition of the resulting deposits were characterized.