Editors’ Choice—4D Neutron and X-ray Tomography Studies of High Energy Density Primary Batteries: Part I. Dynamic Studies of LiSOCl2 during Discharge

The understanding of dynamic processes in Li-metal batteries is an important consideration to enable the full capacity of cells to be utilised. These processes, however, are generally not directly observable using X-ray techniques due to the low attenuation of Li; and are challenging to visualise using neutron imaging due to the low temporal resolution of the technique. In this work, complementary X-ray and neutron imaging are combined to track the dynamics of Li within a primary Li/SOCl 2 cell. The temporal challenges posed by neutron imaging are overcome using the golden ratio imaging method which enables the identification of Li diffusion in operando . This combination of techniques has enabled an improved understanding of the processes which limit rate performance in Li/SOCl 2 cells and may be applied beyond this chemistry to other Li-metal cells.