Open AccessLiMn0.6Fe0.4PO4/CA Cathode Materials with Carbon Aerogel as Additive Synthesized by Wet Ball-Milling Combined with Spray Drying
Author(s) -
Zhenfei Li,
Xiaoyong Ren,
Weichao Tian,
Yi Zheng,
Liwei An,
Jiachen Sun,
Ruqian Ding,
Wen Liang,
Li Wang,
Guangchuan Liang
Publication year - 2020
Publication title -
journal of the electrochemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.258
H-Index - 271
eISSN - 1945-7111
pISSN - 0013-4651
DOI - 10.1149/1945-7111/ab819e
Subject(s) - aerogel , ball mill , materials science , electrolyte , conductivity , cathode , chemical engineering , carbon fibers , composite number , porosity , electrode , analytical chemistry (journal) , nanotechnology , chemistry , composite material , engineering , chromatography
A LiMn 0.6 Fe 0.4 PO 4 /CA composite with a high tap density and superior electronic conductivity is synthesized by a combination of wet ball-milling, spray drying, and carbothermal reduction with Carbon aerogel (CA) as a carbon additive. CA is a porous nanomaterial with a very large specific surface area. There are 3D network structure between the primary particles of LiMn 0.6 Fe 0.4 PO 4 when CA is used for carbon coating. This 3D network structure not only is beneficial for the improvement of electronic conductivity but also can absorb a large amount of electrolyte, which helps to improve the Li + exchange rate between the electrode and electrolyte. More attention, we found that the primary particles of LiMn 0.6 Fe 0.4 PO 4 coated with CA were more compact than those coated without CA, which greatly improved the tap density of the material. Thus the LiMn 0.6 Fe 0.4 PO 4 /CA composite with appropriate amount of CA exhibits a high tap density of 1.6 g cm −3 and excellent electronic conductivity of 8.5 × 10 −2 S cm −1 simultaneously. Resulting in a high volumetric energy density of 856.1 Wh L −1 at 1 C rate, and discharge capacity of 159.1 mAh g −1 at 0.2 C.